Application

How to meet the higher halogen free flame retardant requirement? Let’s see Javachem®IFR!
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 Polyolefin




As a polymer material, polyolefin has a wide range of applications.


However, most polymer materials are highly flammable and some may release a large amount of harmful gases and smoke when burning, leading to fire hazards that have become a global concern.


Flame retardants help to prevent and reduce fires. With the addition of flame retardants, polymer materials are featured with fire resistance, self-extinguishing, and lessened smoke. It is a common approach in flame retardant technology currently. 


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There are three types of flame retardant for polyolefins



<Bromine Flame Retardants>




Bromine flame retardants are the most widely used and produced in the world, offering advantages of less dosage and highly flame-retardant efficiency. Bromine flame retardants provide better thermal stability and higher flame-retardant efficiency compared with chlorine FR. 






However, common bromine flame retardants generate toxic substances such as hydrogen bromide (HBr), dioxins, and benzofurans during combustion, which are corrosmatchive, irritating, and carcinogenic, posing significant risks to the environment and human health.




<Phosphorus Flame Retardants>


Phosphorus compounds exist in oxidation states, and their decomposition products have strong dehydration effects, causing the polymer surface to carbonize and form a carbon layer that provides flame retardancy. Phosphorus flame retardant also has a plasticizing effect, enabling it halogen free. 





<Halogen-free Intumescent Systems>


IFR is a new flame retardant system, typically composed of acid sources, carbon sources, and gas sources. When heating, the polymer containing this flame retardant forms a uniform carbon foam layer on the surface, which provides heat insulation, oxygen isolation, smoke suppression, and prevents molten drips, thus delivering excellent flame retardancy.





When application

intumescent flame retardants for polyolefins

faces the following issues:



Inferior compatibility with polymer substrate. Because of incompatibility of intumescent flame retardants and polymers, it leads to a reduction in electrical and insulating properties, especially significant drop in mechanical properties such as tensile strength and impact resistance.


Moisture absorption. For example, in the APP/PER/MA intumescent systems, it is easy to absorb moisture along with stickiness and lower thermal stability. Moreover, the components are prone to alcoholysis, causing inferior water resistance in flame-retardant polymers.


Based on low molecular weight, the common intumescent flame retardants tend to migrate to the polymer surface and deteriorate the physical and mechanical properties, particularly affecting the appearance.





Thus, developing efficient halogen-free intumescent flame retardant

is a key direction for the development of the flame retardant industry



Javachem®IFR

Halogen-free phosphorus-nitrogen intumescent flame retardant


Javachem®IFR combines carbon source, gas source and acid source into one, which has excellent intumescent char-forming flame-retardant effect. It foams and expands when burning, forming a porous foam char layer on the material surface to block oxygen into the burning area and prevent degraded products from overflowing the material surface. It is halogen-free and eco-friendly, has good compatibility with polyolefin materials. Characterized by low exudation, no moisture absorption and high thermal stability, it does not affect the mechanical properties of materials while delivering excellent flame retardancy.





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